New bimetallic complexes of late transition metals involving pyrazole-bridged bis N-heterocyclic carbene ligands.
نویسندگان
چکیده
Bimetallic Ni, Rh, and Ir complexes of pyrazolate biscarbene containing bulky substituents have been synthesized and characterized by X-ray crystallography; the Ni complex dimerizes to a highly congested L(2)Ni(2) structure, whereas the corresponding Rh and Ir complexes form bimetallic LM(2) structures.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 4 شماره
صفحات -
تاریخ انتشار 2008